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Can someone help me with OChem? I need to propose a mechanism for the reactions in pic related, i'm pretty sure it's Sn1 but i get lost at the carbocation rearrangement.
>>8955400
Brainlet
It's sn2
Although I can see why you would get that wrong
t. Biochem PhD Candidate
>>8955400
here you go OP, i colored the sigma bond involved in and adjacent to bond breaking to make it easier to understand
>>8955485
it's sn1
>>8955485
>sn2
>2 stereoisomers
oh you
>>8955485
>Biochemists in charge of knowing shit about OChem.
>>8955833
Thanks a lot anon
>>8955833
How does that first mechanism make sense? The carbocation should be at the tertiary centre after rearrangement.
>>8955833
>>8955993
oh fuck I'm retarded, nevermind
>>8955485
>sn2
>rearrangement
>2 stereoisomers
turbo brainlet
>>8955993
>>8955994
its correct though
If you'd get a tertiary carbocation instead, you wouldn't get the product seen in the OP pic. It works because of ring strain. In reality, some of that 5-membered ring secondary carbocation would still undergo further rearrangement to give the tertiary carbocation (and then tertiary alcohol) though.