Offered to talk to CEO aftter rejection

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>2 interviews
>felt like I did really good
>Seemed like they really liked me
>Get rejection email
>say "thanks foe letting me, know I'd love to here about future positions if they arise"
>Get email asking if I'd like to talk to the CEO of the company next day. No real reason given as to why.
>Say "sure"

Like why? I honestly don't give a shit if there's no prospect of employment for me. Seemed rude to say no though.

What should I expect? Is this a thing? They said nothing about an available position and it feels like some weird consultation prize because the interviewer really liked me or something. The fuck do I want to talk to the CEO on Skype for an hour for?

I've been unemployed for three months getting "WOW WE REALLY LOVED YOU! but We are going with someone cheaper/different skill set/more experienced/less experienced/lol you do exactly what we need but no becasue reasons/let me refer you to my friend who runs X company, but actually you'll never hear from me again" and would rather jack off or kill myself.

I guess I just roll in like it's a job interview? I have literally nothing I want to ask this person, I just want money.