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Can you deduce the color of a substance from only knowing it's

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Thread replies: 13
Thread images: 2

Can you deduce the color of a substance from only knowing it's chemical structure? How?
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>>8191565
I'm no chemist but we had to memorize the color of certain molecules

If I'm not wrong: permanganate __ purple.

So its a question of seeing the elements in different experiments...
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>>8191565
The complexity and size of the attached molecules bend light (refraction) to generate what we see as color. Bright and vivid colors tend to be from very complexly-chained compounds. Why simple chemicals are colorless (water, air, alcohol, vinegar, etc.)
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>>8191580
Continued: This also means that compounds with the exact same molecules can have a different color. This is due to a different structure. Example: if the same chemical say H10SeC5Ni had two structures. One structure was a straight line while another was in the shape of a polygon. Both would be different colors (say orange and blue). The color depends on light hitting the compound then being refracted.
>>
pretty simple
you wold have to build a "wave tracing " simulation
that would be capable of adding sin functions and calculate diffration and refraction and just shoot a ray of light on your molecule to see what wave lenghts end up at the end
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>>8191604
samefag of course you wold need to know the shape of your molecule
wich is pretty easy to do i think
im not a chemist but we had to learn the shape of h20 and other molécules in chem class with all the angles and stuff
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>>8191583
>>8191604
>>8191607

these, its more dependent on the shape.

>>8191575
this anon is right, but its too general. permanganate changes colors under different temperatures and other molecules do as well. so if you are trying to look at a sketch of an organic molecule and determine the color, you arent going to be able to do it
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>>8191604
>you wold have to build a "wave tracing " simulation
Wouldn't it be more complicated than that? I mean at those small scales we have to expect quantum effects, and I doubt that we possess enough computational power to accurately simulate this.
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File: 1467941769823.jpg (34KB, 368x417px) Image search: [Google]
1467941769823.jpg
34KB, 368x417px
Lmfao you're all retarded
>mfw math and physics majors think they can opine on any subject as if they have any sort of understanding

Look up Woodward's rules OP, and ligand/crystal field theory
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>>8191565
Yes, things have color because of chemical reactions.
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>>8191565
By looking at it irl
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>>8193354
Larger structures on the order of 100nm in size effect the color of the substance just as much as the absorption properties of the individual molecules.

https://www.youtube.com/watch?v=DOSWHyCVX-o

Vertically aligned nanotube arrays trap light of a wide range of frequencies long enough for all of it to be absorbed.
>>
The simplest example is graphene and diamond. They're both just carbon, but have incredibly different properties. You can find the colors of these things from a purely theoretical standpoint. I assert that this treatment belongs more in condensed matter physics than chemistry. But Im a little biased.
Thread posts: 13
Thread images: 2


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