Is there anything wrong with doing my compounds in the morning and accessories in the afternoon or at night?
Yeah, it turns you into a faggot that posts anime pictures
>>42458680
A few people I know do morning and evening workouts. Not normally for splitting compounds from isolations, but more for separate muscle groups such as arms and back.
Long story short, I don't see the problem with wanting to do your best in compounds first thing and then recuperating for isolations much later in the day. Just make sure that your workouts take in account for what you are doing timescale wise.
>>42458726