I've been playing Pokemon for a couple days in my city and

Show her your 10 CP Rattata

Ask her if she plays or something, make an excuse to talk to her and try to keep it going. If she's not interested that sucks but don't follow her around or anything

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>Hey, I've seen you around here a few times. You're playing Pokemon Go, right?

Just say that. You've been given an icebreaker that dudes would have killed for in ages past. From there just let a conversation happen. It may feel hard or nerve-wracking but that's what you have to do, man.

Just chat for a while and eventually ask if she'd like to walk around with you while you play.

If you hit it off, ask for her number when you decide to split ways.

Boss move: "I'm about to drop a module on a Pokestop up here, you should stick around"

Other possible things to say/ask:
>So are you Instinct/whatever the other two are called?
>Check out my team (move in a little close, but don't be creepy)
>Do you know of any good spots around town?