If you are wanting to do portraits or life painting, Id go for Burnt Sienna, Burnt Umber and Yellow Ochre, vermillion, prussian blue, opaque white, paynes gray, cadmium yellow and a purple, I use purple lake but I think thats a W&N exclusive.
For easy mixing get a warm and cool of each primary and other colors you find convenient, eg. cad red and alizarin crimson, french ultramarine and cerulean blue, etc. Whatever you decide to get I recommend also getting a tube of burnt umber and either yellow ochre or raw sienna, maybe burnt sienna as well.
If you're filling empty pans I wouldn't buy Sennelier, since the honey in the paints will prevent the pans from drying properly.
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